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- W2610796445 abstract "In the present investigation, densities (ρ), speeds of sound (u) and refractive index (nD) for the binary blends of 1-Butyl-3-methylimidazolium trifluoromethanesulfonate[Bmim][OTf], an ionic liquid, with diethylene glycol monomethyl ether (DEGMME) and diethylene glycol monoethyl ether (DEGMEE) are reported over the entire range of composition, at temperatures ranging from 298.15 to 323.15 K and at 0.1 MPa pressure. From the experimental data, various excesses function like excess molar volume (VmE), excess isentropic compressibilities (κsE), excess molar isentropic compressibilities (Ks , mE), excess speed of sound (uE), and deviation in refractive index (ΔnD) are calculated. Excess functions are fitted with Redlich-Kister polynomial equation to obtain the binary coefficients and the standard errors. Excess partial molar volumes (V¯m,1E and V¯m,2E) and their limiting values at infinite dilution (V¯m,10,E andV¯m,20,E) are calculated from the experimental density measurements. Excess partial molar isentropic compression, K¯s,m,1E and K¯s,m,2E of both components and their respective limits at infinite dilution, K¯s,m,10,E and K¯s,m,20,E, are obtained. The nature of molecular interactions in the binary mixtures are investigated adopting FT-IR spectroscopic data especially from the view point of the associations and disassociations of intramolecular H-bondings in the alkoxyalkanol molecules by the progressive addition of the ionic liquid in the blends." @default.
- W2610796445 created "2017-05-12" @default.
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- W2610796445 date "2017-07-01" @default.
- W2610796445 modified "2023-10-18" @default.
- W2610796445 title "Volumetric, acoustic and spectroscopic study of 1-butyl-3-methylimidazolium trifluoromethanesulfonate with alkoxyalkanols at different temperatures" @default.
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- W2610796445 doi "https://doi.org/10.1016/j.molliq.2017.04.129" @default.
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