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- W2610973411 abstract "Exciplexes of 2,6,9,10-tetracyanoanthracene (TCA) with alkylbenzenes were investigated in solvents ranging from cyclohexane to acetonitrile. Plots of the reduced emission maxima or the average emission frequency (hνav) versus redox potential differences (Eredox) were linear with a slope of ∼1 in all solvents, which is consistent with the highly ionic character of the exciplexes. The exciplex spectra were analyzed in terms of the energy gap between the exciplex minimum and the AD pair (ΔG), the energy difference between ΔG and Eredox (δEx), and the total reorganization energy (Σλ). A plot of (Eredox - hνav), equivalent to (Σλ - δEx), versus a solvent polarity function showed a linear dependency for the low-to-moderate polarity solvents, whereas highly polar solvents deviated significantly. δEx showed a smooth linear dependency for all solvents. Thus, the deviation of the polar solvents is due to a larger-than-expected Σλ. Additionally, the full width at half-maximum (fwhm) of the emission spectra in polar solvents deviates significantly from the extrapolated trend in less-polar solvents. The deviations of Σλ and fwhm in highly polar solvents can plausibly be explained by composite emissions from two exciplex structures, with the donor overlapping with the inner or outer ring of TCA." @default.
- W2610973411 created "2017-05-12" @default.
- W2610973411 creator A5011626049 @default.
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- W2610973411 date "2017-05-05" @default.
- W2610973411 modified "2023-09-27" @default.
- W2610973411 title "Multiple Intermolecular Exciplexes in Highly Polar Solvents" @default.
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- W2610973411 doi "https://doi.org/10.1021/acs.jpca.7b01461" @default.
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