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• W2611118737 endingPage "457" @default.
• W2611118737 startingPage "441" @default.
• W2611118737 abstract "We describe the use of dicyanoaurate ions as linear ditopic metal–organic acceptors for the halogen bond-driven assembly of a dichroic metal–organic cocrystal based on azobenzene chromophores. Structural analysis by single crystal X-ray diffraction revealed that the material is a four-component solid, consisting of anticipated anionic metal–organic halogen-bonded chains based on dicyanoaurate ions, as well as complex potassium-based cations and discrete molecules of the crown ether 15-crown-5. Importantly, the structural analysis revealed the parallel alignment of the halogen-bonded chains required for dichroic behaviour, confirming that crystal engineering principles developed for the design of halogen-bonded dichroic organic cocrystals are also applicable to metal-based structures. In the broader context of crystal engineering, the structure of the herein reported dichroic material is additionally interesting as the presence of an ion pair, a neutral azobenzene and a molecule of a room-temperature liquid make it an example of a solid that simultaneously conforms to definitions of a salt, a cocrystal, and a solvate." @default.
• W2611118737 created "2017-05-12" @default.
• W2611118737 creator A5007640798 @default.
• W2611118737 creator A5044298471 @default.
• W2611118737 creator A5050264456 @default.
• W2611118737 creator A5076284262 @default.
• W2611118737 creator A5082833054 @default.
• W2611118737 creator A5085401444 @default.
• W2611118737 creator A5087518548 @default.
• W2611118737 creator A5088974934 @default.
• W2611118737 date "2017-01-01" @default.
• W2611118737 modified "2023-09-26" @default.
• W2611118737 title "Assembly and dichroism of a four-component halogen-bonded metal–organic cocrystal salt solvate involving dicyanoaurate(I) acceptors" @default.
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• W2611118737 doi "https://doi.org/10.1039/c7fd00114b" @default.

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