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- W2611248932 abstract "An efficient BF3 · Et2O-catalyzed divergent synthesis of sulfinate esters and sulfones through C–O and C–S bond formation has been achieved from alcohols and p-toluenesulfonylmethyl isocyanide (TosMIC). Various alcohols reacted smoothly with TosMIC under the present conditions at room temperature providing sulfinate esters exclusively. By tuning the reaction temperature, the alcohols that provide highly stabilized carbocation in the reaction medium afforded sulfones as sole products. This study was aimed at understanding the regioselectivity of ambidentate sulfinate ion and to elucidate the interpretation of sulfinate/sulfone scaffolds." @default.
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- W2611248932 date "2017-05-31" @default.
- W2611248932 modified "2023-09-26" @default.
- W2611248932 title "Substrate- and temperature-controlled divergence in reactions of alcohols with TosMIC catalyzed by BF<sub>3</sub> · Et<sub>2</sub>O: Facile access to sulfinates and sulfones" @default.
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- W2611248932 doi "https://doi.org/10.1080/00397911.2017.1321128" @default.
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