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• W2611559187 endingPage "89" @default.
• W2611559187 startingPage "79" @default.
• W2611559187 abstract "Ar-BIANs and related α-diimine Co complexes were wet impregnated onto Vulcan® XC 72 R carbon black powder and used as precursors for the synthesis of heterogeneous supported nanoscale catalysts by pyrolysis under argon at 800 °C. The catalytic materials feature a core-shell structure composed of metallic Co and Co oxides decorated with nitrogen-doped graphitic layers (NGr). These catalysts display high activity in the liquid phase hydrogenation of aromatic nitro compounds (110 °C, 50 bar H2) to give chemoselectively substituted aryl amines. The catalytic activity is closely related to the amount and type of nitrogen atoms in the final catalytic material, which suggests a heterolytic activation of dihydrogen." @default.
• W2611559187 created "2017-05-12" @default.
• W2611559187 creator A5005182277 @default.
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• W2611559187 creator A5085324741 @default.
• W2611559187 creator A5089810655 @default.
• W2611559187 date "2017-07-01" @default.
• W2611559187 modified "2023-09-25" @default.
• W2611559187 title "Co-based heterogeneous catalysts from well-defined α-diimine complexes: Discussing the role of nitrogen" @default.
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