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• W2611700387 abstract "A sunlight induced simple green route has been developed for the synthesis of polyacrylate functionalized gold nanoparticles (PAA-AuNPs), in which poly(acrylic acid) functions as a reducing as well as stabilizing agent. This material has been characterized on the basis of spectroscopic and microscopic studies; it exhibited selective colorimetric detection of Al3+ in aqueous media, and the Al3+ induced aggregated PAA-AuNPs exhibited detection of F– with sharp color change and high selectivity and sensitivity out of a large number of metal ions and anions tested. The mechanistic study revealed that, for Al3+, the color change is due to a shift of the SPR band because of the Al3+ induced aggregation of PAA-AuNPs, whereas for F–, the reverse color change (blue to red) with return of the SPR band to its original position is due to dispersion of aggregated PAA-AuNPs, as F– removes Al3+ from the aggregated species by complex formation. Only concentration-dependent fluoride ion can prevent Al3+ from aggregating PAA-AuNPs. The method is successfully used for the detection of F– in water collected from various sources by the spiking method, in toothpastes of different brands by the direct method. The solid Al3+-PAA-AuNPs were isolated, adsorbed on ZIF@8 (zeolitic imidazolate framework) and on a cotton strip, and applied as solid sensing material for detection of F– in aqueous media." @default.
• W2611700387 created "2017-05-12" @default.
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• W2611700387 date "2017-05-15" @default.
• W2611700387 modified "2023-10-03" @default.
• W2611700387 title "Sunlight Induced Preparation of Functionalized Gold Nanoparticles as Recyclable Colorimetric Dual Sensor for Aluminum and Fluoride in Water" @default.
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• W2611700387 doi "https://doi.org/10.1021/acsami.7b02742" @default.
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