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- W2611873873 abstract "Abstract A concise, protecting‐group‐free total synthesis of the unusual brominated sesquiterpene aplydactone is described. Our synthesis features a [2+2] photocycloaddition, a Wolff ring contraction, an unusual remote C−H functionalization to establish the highly strained tetracyclic core, and a hydrogen‐atom transfer (HAT) reaction to access the bromine‐containing stereocenter. A finely tuned conformation of the α‐diazoketone precursor is the key for the success of the late‐stage transannular C−H insertion to deliver a bridged six‐membered ring and a quaternary stereocenter (C6) between two quaternary carbon atoms (C1 and C7)." @default.
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- W2611873873 date "2017-05-23" @default.
- W2611873873 modified "2023-10-10" @default.
- W2611873873 title "Total Synthesis of Aplydactone by a Conformationally Controlled C−H Functionalization" @default.
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- W2611873873 doi "https://doi.org/10.1002/anie.201703803" @default.
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