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- W2612994080 abstract "We report herein the first Lewis acid-catalyzed generation of 2-amidoallyl cations through ring-opening of 4-benzylidene-2-oxazolines with Sc(OTf)3. Upon nucleophilic addition of indoles, indolylenamides were obtained with yields of 60–99% and excellent (Z)-selectivity. In addition, the novel strategy was also successfully applied to pyrroles and naphthols as π-nucleophiles. A Brønsted acid-catalyzed process using TfOH formed in situ was ruled out by control experiments." @default.
- W2612994080 created "2017-05-19" @default.
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- W2612994080 date "2017-05-22" @default.
- W2612994080 modified "2023-09-24" @default.
- W2612994080 title "Lewis Acid-Catalyzed Nucleophilic Addition of Indoles to in Situ-Generated 2-Amidoallyl Cations" @default.
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- W2612994080 doi "https://doi.org/10.1021/acs.joc.7b00791" @default.
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