Matches in SemOpenAlex for { <https://semopenalex.org/work/W2613017300> ?p ?o ?g. }
- W2613017300 endingPage "5212" @default.
- W2613017300 startingPage "5204" @default.
- W2613017300 abstract "Although closely related to polystyrene, poly(divinylbenzene) (PDVB) has found limited utility due to the difficulties associated with its synthesis. As a highly cross-linked polymer, PDVB is infusible and insoluble and thus nearly impossible to shape into films by either melt or solvent-based processes. Here, we report the initiated chemical vapor deposition (iCVD) of nearly stress-free, highly transparent, free-standing films of PDVB up to 25 μm thick. Films initially grow under tensile intrinsic stress but become more compressive with thickness and eventually converge to zero-stress values once they reach ≥10 μm in thickness. Upon initial heating, the evaporative loss of unreacted monomer left in the polymer matrix induces between 35 and 45 MPa of tensile stress in the films. Afterward, subsequent heating cycles induce reversible stress and film expansion behaviors. We estimate the degree of cross-linking to be 44%, resulting in high thermal stability (up to 300 °C) and mechanical stiffness (Young’s modulus of 5.2 GPa). The low stress combined with high cross-linking makes iCVD PDVB an excellent candidate for protective coatings in harsh environments." @default.
- W2613017300 created "2017-05-19" @default.
- W2613017300 creator A5017045811 @default.
- W2613017300 creator A5027095938 @default.
- W2613017300 creator A5057406418 @default.
- W2613017300 creator A5060927291 @default.
- W2613017300 creator A5061016942 @default.
- W2613017300 creator A5067164690 @default.
- W2613017300 creator A5084898506 @default.
- W2613017300 date "2017-05-18" @default.
- W2613017300 modified "2023-10-12" @default.
- W2613017300 title "Ultralow Stress, Thermally Stable Cross-Linked Polymer Films of Polydivinylbenzene (PDVB)" @default.
- W2613017300 cites W1973145051 @default.
- W2613017300 cites W1973528684 @default.
- W2613017300 cites W1976989494 @default.
- W2613017300 cites W1977726516 @default.
- W2613017300 cites W1981694149 @default.
- W2613017300 cites W1987511264 @default.
- W2613017300 cites W1987654219 @default.
- W2613017300 cites W1993992265 @default.
- W2613017300 cites W1995669028 @default.
- W2613017300 cites W1996915400 @default.
- W2613017300 cites W2004605090 @default.
- W2613017300 cites W2009847928 @default.
- W2613017300 cites W2010088602 @default.
- W2613017300 cites W2025424764 @default.
- W2613017300 cites W2030087442 @default.
- W2613017300 cites W2032568915 @default.
- W2613017300 cites W2036818315 @default.
- W2613017300 cites W2041104540 @default.
- W2613017300 cites W2052137108 @default.
- W2613017300 cites W2060335477 @default.
- W2613017300 cites W2060430942 @default.
- W2613017300 cites W2066874036 @default.
- W2613017300 cites W2076629076 @default.
- W2613017300 cites W2078801606 @default.
- W2613017300 cites W2086933933 @default.
- W2613017300 cites W2089468913 @default.
- W2613017300 cites W2089531961 @default.
- W2613017300 cites W2106591441 @default.
- W2613017300 cites W2109319786 @default.
- W2613017300 cites W2126947909 @default.
- W2613017300 cites W2158553031 @default.
- W2613017300 cites W2162348177 @default.
- W2613017300 cites W2222600977 @default.
- W2613017300 cites W2319344100 @default.
- W2613017300 cites W2327099131 @default.
- W2613017300 cites W2333566406 @default.
- W2613017300 cites W2500846513 @default.
- W2613017300 doi "https://doi.org/10.1021/acs.langmuir.7b01403" @default.
- W2613017300 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28489409" @default.
- W2613017300 hasPublicationYear "2017" @default.
- W2613017300 type Work @default.
- W2613017300 sameAs 2613017300 @default.
- W2613017300 citedByCount "11" @default.
- W2613017300 countsByYear W26130173002018 @default.
- W2613017300 countsByYear W26130173002019 @default.
- W2613017300 countsByYear W26130173002021 @default.
- W2613017300 countsByYear W26130173002022 @default.
- W2613017300 crossrefType "journal-article" @default.
- W2613017300 hasAuthorship W2613017300A5017045811 @default.
- W2613017300 hasAuthorship W2613017300A5027095938 @default.
- W2613017300 hasAuthorship W2613017300A5057406418 @default.
- W2613017300 hasAuthorship W2613017300A5060927291 @default.
- W2613017300 hasAuthorship W2613017300A5061016942 @default.
- W2613017300 hasAuthorship W2613017300A5067164690 @default.
- W2613017300 hasAuthorship W2613017300A5084898506 @default.
- W2613017300 hasBestOaLocation W26130173002 @default.
- W2613017300 hasConcept C112950240 @default.
- W2613017300 hasConcept C127413603 @default.
- W2613017300 hasConcept C138885662 @default.
- W2613017300 hasConcept C15920480 @default.
- W2613017300 hasConcept C159985019 @default.
- W2613017300 hasConcept C166940927 @default.
- W2613017300 hasConcept C178790620 @default.
- W2613017300 hasConcept C185592680 @default.
- W2613017300 hasConcept C188027245 @default.
- W2613017300 hasConcept C192562407 @default.
- W2613017300 hasConcept C21036866 @default.
- W2613017300 hasConcept C2777566558 @default.
- W2613017300 hasConcept C2777682263 @default.
- W2613017300 hasConcept C2777922577 @default.
- W2613017300 hasConcept C2780471494 @default.
- W2613017300 hasConcept C41895202 @default.
- W2613017300 hasConcept C42360764 @default.
- W2613017300 hasConcept C521977710 @default.
- W2613017300 hasConcept C59061564 @default.
- W2613017300 hasConceptScore W2613017300C112950240 @default.
- W2613017300 hasConceptScore W2613017300C127413603 @default.
- W2613017300 hasConceptScore W2613017300C138885662 @default.
- W2613017300 hasConceptScore W2613017300C15920480 @default.
- W2613017300 hasConceptScore W2613017300C159985019 @default.
- W2613017300 hasConceptScore W2613017300C166940927 @default.
- W2613017300 hasConceptScore W2613017300C178790620 @default.
- W2613017300 hasConceptScore W2613017300C185592680 @default.
- W2613017300 hasConceptScore W2613017300C188027245 @default.
- W2613017300 hasConceptScore W2613017300C192562407 @default.
- W2613017300 hasConceptScore W2613017300C21036866 @default.