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- W2613202477 endingPage "4073" @default.
- W2613202477 startingPage "4066" @default.
- W2613202477 abstract "A series of phthalic acid derivatives (P) with a carbon-chain tail was designed and synthesized as single-component gelators. A combination of the single-component gelator P and a non-gelling additive n-alkylamine A through acid-base interaction brought about a series of novel phase-selective two-component gelators PA. The gelation capabilities of P and PA, and the structural, morphological, thermo-dynamic and rheological properties of the corresponding gels were investigated. A molecular dynamics simulation showed that the H-bonding network in PA formed between the NH of A and the carbonyl oxygen of P altered the assembly process of gelator P. Crude PA could be synthesized through a one-step process without any purification and could selectively gel the oil phase without a typical heating-cooling process. Moreover, such a crude PA and its gelation process could be amplified to the kilogram scale with high efficiency, which offers a practical economically viable solution to marine oil-spill recovery." @default.
- W2613202477 created "2017-05-19" @default.
- W2613202477 creator A5005228021 @default.
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- W2613202477 creator A5077896487 @default.
- W2613202477 date "2017-01-01" @default.
- W2613202477 modified "2023-10-18" @default.
- W2613202477 title "Scaleable two-component gelator from phthalic acid derivatives and primary alkyl amines: acid–base interaction in the cooperative assembly" @default.
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