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• W2613624063 abstract "Aerobic epoxidation of olefins catalyzed by iron complexes without the use of a sacrificial coreductant is unknown. We report the reductive activation of O2 by a bioinspired [(bTAML)FeIII(H2O)]- (1) complex to catalyze the epoxidation of alkenes with TONs of up to 80. Spectroscopic and kinetic evidence indicates the involvement of FeV(O) as the active oxidant during the reaction." @default.
• W2613624063 created "2017-05-19" @default.
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• W2613624063 date "2017-01-01" @default.
• W2613624063 modified "2023-10-16" @default.
• W2613624063 title "Reductive activation of O₂ by a bioinspired Fe complex for catalytic epoxidation reactions" @default.
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• W2613624063 doi "https://doi.org/10.1039/c7cc00933j" @default.
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