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• W2613633463 abstract "A novel glycosyl donor with a triisopropylsilyl (TIPS) nonparticipating group at O-2 is introduced for use in 1,2-cis-galactosylation. Coupling the 2-O-TIPS-substituted thiogalactoside donor with a series of mono- and disaccharide glycosyl acceptors was found to lead exclusively to α-linked oligosaccharides. The observed exceptionally high α-selectivity was interpreted in terms of conformational changes in the glycosyl cation induced by the bulky 2-O-TIPS group." @default.
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• W2613633463 date "2017-05-08" @default.
• W2613633463 modified "2023-10-11" @default.
• W2613633463 title "A Novel Glycosyl Donor with a Triisopropylsilyl Nonparticipating Group in Benzyl-Free Stereoselective 1,2-cis-Galactosylation" @default.
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• W2613633463 doi "https://doi.org/10.1055/s-0036-1589028" @default.
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