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- W2614130862 abstract "Three lanthanide complexes, [H2NMe2]3[Ln(III)(2,6-pyridinedicarboxylate)3] (Ln = Sm, Eu, Tb) have been successfully synthesized using a solvothermal method in the presence of a base and they were prepared from inexpensive and readily available reactants. Infrared, ultraviolet–visible absorption spectroscopies, elemental analyses and thermogravimetric analysis were employed for the characterization. Crystals suitable for X-ray diffraction were isolated in good yields by a simple filtration, their crystal structures were analyzed; the samarium structure has orthorhombic symmetry with space group Pbcn, exhibiting three-dimensional supramolecular architecture through hydrogen bonding interactions. The metal center is coordinated to nine atoms corresponding to three pyridine-2,6-dicarboxylic acid molecules. These compounds are thermally stable up to 270 °C." @default.
- W2614130862 created "2017-05-26" @default.
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- W2614130862 date "2017-10-01" @default.
- W2614130862 modified "2023-10-18" @default.
- W2614130862 title "Solvothermal synthesis and spectroscopic characterization of three lanthanide complexes with high luminescent properties [H 2 NMe 2 ] 3 [Ln(III)(2,6-pyridinedicarboxylate) 3 ] (Ln = Sm, Eu, Tb): In the presence of 4,4′-Bipyridyl" @default.
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- W2614130862 doi "https://doi.org/10.1016/j.molstruc.2017.05.055" @default.
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