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- W2614321853 abstract "Abstract The reaction of CoCl 2 ·6H 2 O with mixed ligands of 2,2′-oxybis(benzoic acid) (2,2′-H2oba) and trans -1,2-bis(4-pyridyl)ethylene (bpe) under hydrothermal conditions produced a new 3D cobalt(II) supramolecular architecture {[Co(oba)(bpe)(H 2 O)]·1/2bpe} n ( 1 ), which was structurally characterized by elemental analysis, infrared spectroscopy, thermogravimetric analyses, and single-crystal X-ray diffraction. The results show that the Co(II) ions are connected to form an infinite polymeric chain by bpe ligands in complex 1 . Due to strong intermolecular O–H···O hydrogen bonds, the adjacent chains are connected to generate a double-chain structure. These double chains are joined by O–H···N hydrogen bonding to produce a 2D supramolecular architecture. Furthermore, through intermolecular C–H···O hydrogen bonds, the layers are linked into a 3D supramolecular structure. Magnetic susceptibility measurements have indicated that complex 1 shows weak antiferromagnetic interactions between adjacent Co(II) ions." @default.
- W2614321853 created "2017-05-26" @default.
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- W2614321853 date "2017-05-24" @default.
- W2614321853 modified "2023-09-23" @default.
- W2614321853 title "A 3D supramolecular architecture based on 2,2′-oxybis(benzoic acid) and trans-1,2-bis(4-pyridyl)ethylene as ligands for Co(II)" @default.
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- W2614321853 doi "https://doi.org/10.1515/znb-2016-0245" @default.
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