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- W2614372380 abstract "1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism." @default.
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- W2614372380 date "2017-05-17" @default.
- W2614372380 modified "2023-09-25" @default.
- W2614372380 title "Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes" @default.
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- W2614372380 doi "https://doi.org/10.1002/zaac.201700049" @default.
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