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- W2615205275 abstract "Abstract Cytochrome P450 enzyme‐copper phosphate hybrid materials with flower‐like shape were prepared with a simple but efficient coprecipitation method. The growth process of the hybrid flowers can be divided into three successive steps: coordination/nucleation, growth, and further ripen. The concentration of enzymes in the mother liquor exerted great influence on the morphology and surface enzyme content of the nano‐composites. The catalytic performance in the reaction of selective oxidation of sulfide to sulfoxide was also investigated. The hybrid flowers exhibited superior catalytic performance: satisfied thioanisole conversion and selectivity to methyl phenyl sulfoxide (both above 97%) with H 2 O 2 as oxidant under mild reaction conditions, excellent stability and recyclability, and wide scope of substrates. Such results indicate that the hybrid materials are potentially good candidates in the industrial enzyme catalysis." @default.
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- W2615205275 date "2017-03-13" @default.
- W2615205275 modified "2023-10-10" @default.
- W2615205275 title "Cytochrome <scp>P450</scp> Enzyme‐Copper Phosphate Hybrid Nano‐Flowers with Superior Catalytic Performances for Selective Oxidation of Sulfides" @default.
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- W2615205275 doi "https://doi.org/10.1002/cjoc.201600714" @default.
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