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- W2615245087 abstract "We report a large kinetic isotope effect at 298 K, kH/kD ≈ 150, associated with an intramolecular 1,5-hydrogen atom transfer (1,5-HAT) in the decay of a PEGylated carbazyl (aminyl) radical in solution. The experimental observations surprisingly combine the hallmarks of tunneling, including large KIEs and unusual activation parameters, with linear Arrhenius and Eyring plots over an exceptionally wide temperature range of 116 K." @default.
- W2615245087 created "2017-05-26" @default.
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- W2615245087 date "2017-05-22" @default.
- W2615245087 modified "2023-10-16" @default.
- W2615245087 title "Intramolecular Hydrogen Atom Transfer in Aminyl Radical at Room Temperature with Large Kinetic Isotope Effect" @default.
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- W2615245087 doi "https://doi.org/10.1021/jacs.7b02692" @default.
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