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• W2615265211 abstract "Abstract A nearly defect-free metal-oxide-based coating structure was made on Al-Mg-Si alloy by plasma electrolytic oxidation at high current density accompanying high-energy plasma sparks. The present coatings were performed at two different current densities of 50 and 125 mA/cm 2 in the alkaline-phosphate-based electrolytes with different concentrations of sodium hexafluoroaluminate (Na 3 AlF 6 ). The addition of (Na 3 AlF 6 ) to the electrolyte used in this study would result in a decrease in the size of the micropore, and a reasonably defect-free coating structure was achieved in the sample treated at high current density of 125 mA/cm 2 . This was attributed mainly to the hydrolysis of AlF 6 3− triggered by intense plasma sparks, which resulted in a uniform distribution of fluorine throughout the coating. Accordingly, the corrosion performance of the coating formed in the electrolyte containing 1.5 g/L Na 3 AlF 6 at 125 mA/cm 2 was improved significantly as confirmed by electrochemical impedance analysis. In addition, the formation mechanism of the nearly defect-free coating in the presence of Na 3 AlF 6 was discussed." @default.
• W2615265211 created "2017-05-26" @default.
• W2615265211 creator A5006178080 @default.
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• W2615265211 date "2017-05-24" @default.
• W2615265211 modified "2023-09-23" @default.
• W2615265211 title "Toward a nearly defect-free coating via high-energy plasma sparks" @default.
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• W2615265211 doi "https://doi.org/10.1038/s41598-017-02702-3" @default.
• W2615265211 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5443762" @default.
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