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• W2615494816 endingPage "1220" @default.
• W2615494816 startingPage "1212" @default.
• W2615494816 abstract "Abstract Luminescence technology has been improved with the help of semiconductor nanoparticles that possess novel optical and electrical properties compared with their bulk counterpart. The aim of this study was to design semiconductor nanocrystals in their pure (ZnS) or doped form (ZnS:Mn) with different concentrations of Mn 2+ ions by a wet chemical route stabilized by ethylenediamine tetra‐acetic acid (EDTA) and to evaluate their luminescence properties. The nanocrystals were characterized by physicochemical techniques such as X‐ray diffraction (XRD), High‐resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SEAD), EDS, and ultraviolet (UV)–visible light and photoluminescence (PL) studies. These results showed the presence of cubic phase and spherically shaped nanocrystals. A blue shift with respect to their bulk counterpart was observed. PL emission spectra were observed with a fixed blue peak and the yellow‐orange bands were red shifted towards the red region under the same excitation wavelength. The orange‐red bands were attributed to the radiation transition of electrons in 3d5 unfilled shells of Mn 2+ ions [ 4 T 1 ( 4 G)‐ 6 A 1 ( 6 S)]; the ZnS matrix varied with Mn 2+ concentration. Shift and increase in the intensity of the PL and absorption bands were observed with increase in Mn content. The study showed that Mn 2+ ‐doped ZnS nanocrystal emission bands can be tuned from the yellow‐orange to the red regions under a controlled synthesis process and could be used as promising luminescent emitters in the biology field upon functionalization with suitable materials. Further studies on construction with various other materials will be useful for practical applications." @default.
• W2615494816 created "2017-05-26" @default.
• W2615494816 creator A5010290440 @default.
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• W2615494816 date "2017-05-16" @default.
• W2615494816 modified "2023-10-18" @default.
• W2615494816 title "Tuneable luminescence properties of EDTA‐assisted ZnS:Mn nanocrystals from a yellow‐orange to a red emission band" @default.
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• W2615494816 doi "https://doi.org/10.1002/bio.3313" @default.
• W2615494816 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28513077" @default.
• W2615494816 hasPublicationYear "2017" @default.
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