Matches in SemOpenAlex for { <https://semopenalex.org/work/W2616088977> ?p ?o ?g. }
- W2616088977 endingPage "165" @default.
- W2616088977 startingPage "107" @default.
- W2616088977 abstract "Abstract A novel bioinspired approach to the development of powerful catalysts for oxidation is based on the N-bridged diiron phthalocyanine and porphyrin complexes. This scaffold is particularly suited for the stabilization of Fe IV Fe IV entities and can therefore be useful for the preparation of oxidizing active species. The possibility of the charge delocalization on two iron sites, two macrocyclic ligands, and the nitrogen bridge makes possible the activation of peroxides including H 2 O 2 . The ultra high-valent diiron-oxo species (L)Fe IV –N–Fe IV (L + ) O (L = phthalocyanine, porphyrin) have been detected at low temperatures and characterized by cryospray MS, UV–vis, EPR, X-ray absorption spectroscopy, and Mossbauer techniques. These highly electrophilic (L)Fe IV –N–Fe IV (L + ) O species show outstanding reactivity. The catalytic applications of μ-nitrido diiron complexes include oxidation of methane and benzene, transformation of aromatic C–F bonds in oxidative conditions, oxidative dechlorination, and formation of C–C bonds. Importantly, all these reactions can be carried out under clean and mild conditions with high conversions and turnover numbers. μ-Nitrido diiron species demonstrate similar mechanistic features ( 18 O labeling, formation of benzene epoxide, and NIH shift in the aromatic oxidation) (see Section 4.4 and Kudrik and Sorokin, 2008 for the explanation) as enzymes operating via high-valent iron-oxo species. μ-Nitrido diiron complexes transform perfluorinated aromatic compounds in oxidative conditions, while the strongest oxidizing enzymes do not. Advanced spectroscopic and reactivity studies confirm the participation of high-valent diiron-oxo species in these catalytic reactions." @default.
- W2616088977 created "2017-05-26" @default.
- W2616088977 creator A5074117197 @default.
- W2616088977 date "2017-01-01" @default.
- W2616088977 modified "2023-09-25" @default.
- W2616088977 title "μ-Nitrido Diiron Phthalocyanine and Porphyrin Complexes: Unusual Structures With Interesting Catalytic Properties" @default.
- W2616088977 cites W1525406977 @default.
- W2616088977 cites W1528474339 @default.
- W2616088977 cites W1787517908 @default.
- W2616088977 cites W1965151304 @default.
- W2616088977 cites W1966278195 @default.
- W2616088977 cites W1966738996 @default.
- W2616088977 cites W1967700647 @default.
- W2616088977 cites W1968369993 @default.
- W2616088977 cites W1969026406 @default.
- W2616088977 cites W1970522028 @default.
- W2616088977 cites W1972127956 @default.
- W2616088977 cites W1972213020 @default.
- W2616088977 cites W1972268630 @default.
- W2616088977 cites W1977597904 @default.
- W2616088977 cites W1981741592 @default.
- W2616088977 cites W1982996670 @default.
- W2616088977 cites W1983098087 @default.
- W2616088977 cites W1984338286 @default.
- W2616088977 cites W1984713897 @default.
- W2616088977 cites W1985180203 @default.
- W2616088977 cites W1986097657 @default.
- W2616088977 cites W1986463221 @default.
- W2616088977 cites W1987791592 @default.
- W2616088977 cites W1989937324 @default.
- W2616088977 cites W1992140550 @default.
- W2616088977 cites W1997974951 @default.
- W2616088977 cites W1998506770 @default.
- W2616088977 cites W2001412029 @default.
- W2616088977 cites W2001631769 @default.
- W2616088977 cites W2003444459 @default.
- W2616088977 cites W2008221002 @default.
- W2616088977 cites W2014397159 @default.
- W2616088977 cites W2015373539 @default.
- W2616088977 cites W2015981085 @default.
- W2616088977 cites W2019585127 @default.
- W2616088977 cites W2020487961 @default.
- W2616088977 cites W2022331086 @default.
- W2616088977 cites W2023549170 @default.
- W2616088977 cites W2024180737 @default.
- W2616088977 cites W2025624441 @default.
- W2616088977 cites W2026593265 @default.
- W2616088977 cites W2028191441 @default.
- W2616088977 cites W2031883822 @default.
- W2616088977 cites W2033825050 @default.
- W2616088977 cites W2034668737 @default.
- W2616088977 cites W2039429840 @default.
- W2616088977 cites W2040887561 @default.
- W2616088977 cites W2041332551 @default.
- W2616088977 cites W2041433990 @default.
- W2616088977 cites W2042545763 @default.
- W2616088977 cites W2045397008 @default.
- W2616088977 cites W2047481428 @default.
- W2616088977 cites W2048786919 @default.
- W2616088977 cites W2051850235 @default.
- W2616088977 cites W2054315762 @default.
- W2616088977 cites W2055918913 @default.
- W2616088977 cites W2056018616 @default.
- W2616088977 cites W2056866121 @default.
- W2616088977 cites W2058642837 @default.
- W2616088977 cites W2061146825 @default.
- W2616088977 cites W2062482634 @default.
- W2616088977 cites W2066491822 @default.
- W2616088977 cites W2075526028 @default.
- W2616088977 cites W2084787090 @default.
- W2616088977 cites W2088183526 @default.
- W2616088977 cites W2091718794 @default.
- W2616088977 cites W2106229887 @default.
- W2616088977 cites W2107968275 @default.
- W2616088977 cites W2120588187 @default.
- W2616088977 cites W2121494212 @default.
- W2616088977 cites W2131058721 @default.
- W2616088977 cites W2133661395 @default.
- W2616088977 cites W2135361855 @default.
- W2616088977 cites W2142040662 @default.
- W2616088977 cites W2144293293 @default.
- W2616088977 cites W2147899939 @default.
- W2616088977 cites W2155860547 @default.
- W2616088977 cites W2161573001 @default.
- W2616088977 cites W2164377983 @default.
- W2616088977 cites W2170105567 @default.
- W2616088977 cites W2278967167 @default.
- W2616088977 cites W2280604583 @default.
- W2616088977 cites W2288233522 @default.
- W2616088977 cites W2293505006 @default.
- W2616088977 cites W2327160402 @default.
- W2616088977 cites W2332057113 @default.
- W2616088977 cites W2466120442 @default.
- W2616088977 cites W2509186101 @default.
- W2616088977 cites W2525009106 @default.
- W2616088977 cites W2950209354 @default.
- W2616088977 cites W3004430686 @default.
- W2616088977 cites W3137899754 @default.