Matches in SemOpenAlex for { <https://semopenalex.org/work/W2616480404> ?p ?o ?g. }
- W2616480404 endingPage "7241" @default.
- W2616480404 startingPage "7238" @default.
- W2616480404 abstract "Abstract The reactivity of Li[Sc(COT′′) 2 ] ( 1 ; COT′′=1,4‐bis(trimethylsilyl)cyclooctatetraenyl) towards CoCl 2 is considerably different from that of related lanthanide triple‐decker sandwich complexes. In addition to the expected triple‐decker complex Sc 2 (COT′′) 3 ( 2 ), the complex Sc 2 {μ‐BTHP}(COT′′) 2 ( 3 ) is formed, which comprises the novel BTHP 2− ligand (BTHP 2− =bis(3,5‐bis(trimethylsilyl)‐1,3a,6,6a‐tetrahydropentalene‐1‐yl)diide or bis(2,7‐bis(trimethylsilyl)bicyclo[3.3.0]octa‐2,7‐dien‐4‐yl)diide, C 16 H 10 (SiMe 3 ) 4 2− ). The formation of 3 is likely facilitated by the fact that scandium prefers η 8 ,η 3 coordination rather than highly symmetric η 8 ,η 8 coordination, and the η 3 ‐coordinated COT′′ ligand in 1 is activated owing to a loss of aromaticity. Acid hydrolysis of 3 leads to air‐stable H 2 BTHP ( 4 )." @default.
- W2616480404 created "2017-05-26" @default.
- W2616480404 creator A5005752122 @default.
- W2616480404 creator A5027356410 @default.
- W2616480404 creator A5030674774 @default.
- W2616480404 creator A5040249530 @default.
- W2616480404 creator A5047069323 @default.
- W2616480404 creator A5050166966 @default.
- W2616480404 creator A5069558116 @default.
- W2616480404 date "2017-05-16" @default.
- W2616480404 modified "2023-10-16" @default.
- W2616480404 title "Scandium-Mediated Formation of a Bis(tetrahydropentalene)" @default.
- W2616480404 cites W1942009472 @default.
- W2616480404 cites W1966779071 @default.
- W2616480404 cites W1974094532 @default.
- W2616480404 cites W1974507669 @default.
- W2616480404 cites W1983067110 @default.
- W2616480404 cites W2008089542 @default.
- W2616480404 cites W2011962561 @default.
- W2616480404 cites W2020153517 @default.
- W2616480404 cites W2020442481 @default.
- W2616480404 cites W2029441969 @default.
- W2616480404 cites W2031999618 @default.
- W2616480404 cites W2038093325 @default.
- W2616480404 cites W2039975551 @default.
- W2616480404 cites W2043781079 @default.
- W2616480404 cites W2049189395 @default.
- W2616480404 cites W2054392476 @default.
- W2616480404 cites W2056467753 @default.
- W2616480404 cites W2065073063 @default.
- W2616480404 cites W2066756827 @default.
- W2616480404 cites W2072174633 @default.
- W2616480404 cites W2077963621 @default.
- W2616480404 cites W2082024019 @default.
- W2616480404 cites W2084853727 @default.
- W2616480404 cites W2088266143 @default.
- W2616480404 cites W2089718567 @default.
- W2616480404 cites W2091711229 @default.
- W2616480404 cites W2094056928 @default.
- W2616480404 cites W2106378981 @default.
- W2616480404 cites W2120809659 @default.
- W2616480404 cites W2121234216 @default.
- W2616480404 cites W2139895028 @default.
- W2616480404 cites W2155102300 @default.
- W2616480404 cites W2167651156 @default.
- W2616480404 cites W2242442224 @default.
- W2616480404 cites W2309655927 @default.
- W2616480404 cites W2318802583 @default.
- W2616480404 cites W2322550264 @default.
- W2616480404 cites W2325288593 @default.
- W2616480404 cites W2326634281 @default.
- W2616480404 cites W2328742488 @default.
- W2616480404 cites W2395420919 @default.
- W2616480404 cites W2395571735 @default.
- W2616480404 cites W2533423808 @default.
- W2616480404 cites W2548439336 @default.
- W2616480404 cites W2577787397 @default.
- W2616480404 cites W2950401164 @default.
- W2616480404 cites W4243426061 @default.
- W2616480404 doi "https://doi.org/10.1002/anie.201703362" @default.
- W2616480404 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28510295" @default.
- W2616480404 hasPublicationYear "2017" @default.
- W2616480404 type Work @default.
- W2616480404 sameAs 2616480404 @default.
- W2616480404 citedByCount "9" @default.
- W2616480404 countsByYear W26164804042018 @default.
- W2616480404 countsByYear W26164804042019 @default.
- W2616480404 countsByYear W26164804042020 @default.
- W2616480404 countsByYear W26164804042021 @default.
- W2616480404 countsByYear W26164804042022 @default.
- W2616480404 crossrefType "journal-article" @default.
- W2616480404 hasAuthorship W2616480404A5005752122 @default.
- W2616480404 hasAuthorship W2616480404A5027356410 @default.
- W2616480404 hasAuthorship W2616480404A5030674774 @default.
- W2616480404 hasAuthorship W2616480404A5040249530 @default.
- W2616480404 hasAuthorship W2616480404A5047069323 @default.
- W2616480404 hasAuthorship W2616480404A5050166966 @default.
- W2616480404 hasAuthorship W2616480404A5069558116 @default.
- W2616480404 hasConcept C116569031 @default.
- W2616480404 hasConcept C142724271 @default.
- W2616480404 hasConcept C145148216 @default.
- W2616480404 hasConcept C155647269 @default.
- W2616480404 hasConcept C170493617 @default.
- W2616480404 hasConcept C178790620 @default.
- W2616480404 hasConcept C179104552 @default.
- W2616480404 hasConcept C185592680 @default.
- W2616480404 hasConcept C192386470 @default.
- W2616480404 hasConcept C201770740 @default.
- W2616480404 hasConcept C204787440 @default.
- W2616480404 hasConcept C24961977 @default.
- W2616480404 hasConcept C2776910235 @default.
- W2616480404 hasConcept C2777000832 @default.
- W2616480404 hasConcept C32909587 @default.
- W2616480404 hasConcept C551831248 @default.
- W2616480404 hasConcept C55493867 @default.
- W2616480404 hasConcept C71240020 @default.
- W2616480404 hasConcept C71924100 @default.
- W2616480404 hasConcept C8010536 @default.