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- W2616480762 abstract "Furfuryl carbamates are labile and require care to be accessed by activating furfuryl alcohols. An alternative oxanorbornadiene (OND)-based strategy is presented for the preparation of 5-R-substituted furfuryl carbamates via the reactions of amines with intermediate OND carbonates. The resulting OND carbamates, which are stable for several months, undergo thiol mediated retro-Diels-Alder reaction to deliver the desired furfuryl carbamates in a single flask. Conditions for the selective hydrolysis of furfuryl carbamates in the presence of tert-butyloxycarbonyl (Boc) groups were identified, and it was shown that furfuryl carbamates can be used as a prodrug handle." @default.
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- W2616480762 date "2017-05-16" @default.
- W2616480762 modified "2023-10-16" @default.
- W2616480762 title "Synthesis and Reactivity of 5-Substituted Furfuryl Carbamates via Oxanorbornadienes" @default.
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- W2616480762 doi "https://doi.org/10.1021/acs.orglett.7b00990" @default.
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