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- W2616669765 abstract "A Co(II)-based coordination polymer with tetranuclear cobalt(II)-malonate cluster has been easily generated by aqueous medium self-assembly from Cobalt(II) chloride hexahydrate and malonic acid. The structure exhibits a non-interpenetrating, highly undulating two-dimensional (2D) bi-layer network with (4,4) topology. The crystal structure is composed of infinite interdigitated 2D metal–organic bi-layers which extended to an intricate 3D framework through the interbilayer hydrogen bonds. We have studied energetically by means of Density Functional Theory (DFT) calculations the H-bonding interactions that connect the 2D metal–organic bi-layers. The finite theoretical models have been used to compute conventional O‒H∙∙∙O and unconventional C‒H∙∙∙O interactions which plays a key role to build 3D architecture." @default.
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- W2616669765 date "2017-05-19" @default.
- W2616669765 modified "2023-10-16" @default.
- W2616669765 title "Exploring 3D non-interpenetrated metal–organic framework with malonate-bridged Co(II) coordination polymer: structural elucidation and theoretical study" @default.
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- W2616669765 doi "https://doi.org/10.1080/01411594.2017.1326603" @default.
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