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- W2616672232 abstract "An unprecedented stable neutral radical nickel(II) complex of 3,5-bis(dimedonyl)azadiisoindomethene (1) was prepared by the direct reaction between 1,3-diiminoisoindoline and dimedone. A new radical complex 1 has an intense and narrow absorption at 1008 nm and can be reduced to a less stable anionic [1]− with a typical aza(dibenzo)boron dipyrromethene (aza-BODIPY) UV−vis spectrum. Complex 1, along with two other colored condensation reaction products 2 and 3, was characterized by spectroscopy and X-ray crystallography, while the paramagnetic nature of 1 was probed by EPR and SQUID methods. Complex 1 forms dimers in the solid state with short (∼3.16 Å) Ni---Ni contacts. Redox data on 1 are indicative of a reversible reduction process in this complex; its magnetism suggests a S = 1/2 state with the spin density delocalized over the aza-BODIPY core. The experimental data 1 and [1]− were correlated with the density functional theory (DFT) and time-dependent DFT calculations." @default.
- W2616672232 created "2017-05-26" @default.
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- W2616672232 date "2017-05-19" @default.
- W2616672232 modified "2023-10-18" @default.
- W2616672232 title "Direct Synthesis of an Unprecedented Stable Radical of Nickel(II) 3,5-Bis(dimedonyl)azadiisoindomethene with Strong and Narrow Near-Infrared Absorption at λ ∼ 1000 nm" @default.
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- W2616672232 doi "https://doi.org/10.1021/acs.inorgchem.7b01140" @default.
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