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- W2617255369 abstract "The ternary selenide Ba4Ga2Se8 has been synthesized by reaction of BaSe, Ga2Se3, and Se at 1023 K. Single-crystal X-ray diffraction analysis revealed a monoclinic structure (space group P21/c, Z=4, a=13.2393(5) Å, b=6.4305(2) Å, c=20.6432(8) Å, β=104.3148(6)°) featuring one-dimensional chains of corner-sharing Ga-centered tetrahedra and discrete Se22− anionic units, with charge-compensating Ba2+ cations located between them. The UV/vis/NIR diffuse reflectance spectrum reveals an optical band gap of 1.63(2) eV, which is consistent with the black color of the crystals and agrees with a calculated gap of 1.51 eV obtained from band structure calculations. The presence of the Se22− units narrows the band gap in Ba4Ga2Se8 relative to other Ba–Ga–Se phases." @default.
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- W2617255369 date "2016-05-01" @default.
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- W2617255369 title "Ba4Ga2Se8: A ternary selenide containing chains and discrete <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si0003.gif overflow=scroll><mml:mrow><mml:msubsup subscriptshift=90% superscriptshift=90%><mml:mrow><mml:mi mathvariant=normal>S</mml:mi><mml:mi mathvariant=normal>e</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo form=prefix>−</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> units" @default.
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- W2617255369 doi "https://doi.org/10.1016/j.jssc.2016.02.014" @default.
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