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- W2617262641 abstract "We report here a synthetic ion channel developed from a shape-persistent porphyrin-based covalent organic cage. The cage was synthesized by employing a synthetically economical dynamic covalent chemistry (DCC) approach. The organic cage selectively transports biologically relevant iodide ions over other inorganic anions by a dehydration-driven, channel mechanism as evidenced by vesicle-based fluorescence assays and planar lipid bilayer-based single channel recordings. Furthermore, the organic cage appears to facilitate iodide transport across the membrane of a living cell, suggesting that the cage could be useful as a biological tool that may replace defective iodide channels in living systems." @default.
- W2617262641 created "2017-06-05" @default.
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- W2617262641 date "2017-05-26" @default.
- W2617262641 modified "2023-09-29" @default.
- W2617262641 title "Iodide-Selective Synthetic Ion Channels Based on Shape-Persistent Organic Cages" @default.
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- W2617262641 doi "https://doi.org/10.1021/jacs.7b02708" @default.
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