Matches in SemOpenAlex for { <https://semopenalex.org/work/W2617492878> ?p ?o ?g. }
- W2617492878 endingPage "351" @default.
- W2617492878 startingPage "342" @default.
- W2617492878 abstract "Abstract The influence of the counterions on the geometry of Cu(I) and Cu(II) unsubstituted phen-based (phen = 1,10-phenanthroline) complexes was investigated. The synthetic strategy used afforded the synthesis of both the tetracoordinated Cu(I) and pentacoordinated Cu(II) species with general formula [(phen)2Cu]+Y− (Y− = ClO4−, I−, SCN− and BF4−) and [(phen)2CuX]+Y− (X = Cl−, I−, NCS−, and Y− = ClO4−, I−, SCN− and BF4−), respectively. The firstly isolated Cu(I) complexes were characterized by IR, 1H NMR and UV-Vis spectroscopies, their proposed structures being confirmed by elemental analysis, atomic absorption spectroscopy (AAS) and thermogravimetric analysis (TGA). The molecular structure of Cu(II) complexes was determined by single crystal X-ray diffraction analysis. While for Cu(I) complexes, the coordinating nature of the counterions seems to have a strong influence (observed in the solid state and concentrated solution) on the flattening distortion (D2d → D2) of the geometry about the Cu(I) ion, in the Cu(II) derivatives, the size, shape, number and type of intermolecular interactions established by the counterions, drive not only the overall cations supramolecular organization, but also the molecular stereochemistry around the Cu(II) ion." @default.
- W2617492878 created "2017-06-05" @default.
- W2617492878 creator A5011020902 @default.
- W2617492878 creator A5023603809 @default.
- W2617492878 creator A5036342296 @default.
- W2617492878 creator A5057581236 @default.
- W2617492878 creator A5068080494 @default.
- W2617492878 creator A5070005792 @default.
- W2617492878 creator A5074901927 @default.
- W2617492878 creator A5077319795 @default.
- W2617492878 creator A5087638225 @default.
- W2617492878 date "2018-01-01" @default.
- W2617492878 modified "2023-10-18" @default.
- W2617492878 title "Influence of the counterion on the geometry of Cu(I) and Cu(II) complexes with 1,10-phenanthroline" @default.
- W2617492878 cites W165651719 @default.
- W2617492878 cites W1969919479 @default.
- W2617492878 cites W1971032041 @default.
- W2617492878 cites W1971959183 @default.
- W2617492878 cites W1973229047 @default.
- W2617492878 cites W1973238436 @default.
- W2617492878 cites W1980642168 @default.
- W2617492878 cites W1983516146 @default.
- W2617492878 cites W1984883623 @default.
- W2617492878 cites W1991234420 @default.
- W2617492878 cites W1992143807 @default.
- W2617492878 cites W1992907826 @default.
- W2617492878 cites W1998722626 @default.
- W2617492878 cites W2001413583 @default.
- W2617492878 cites W2004977643 @default.
- W2617492878 cites W2013339766 @default.
- W2617492878 cites W2014908042 @default.
- W2617492878 cites W2016616196 @default.
- W2617492878 cites W2019236557 @default.
- W2617492878 cites W2019965820 @default.
- W2617492878 cites W2030775042 @default.
- W2617492878 cites W2031193444 @default.
- W2617492878 cites W2035956261 @default.
- W2617492878 cites W2038452456 @default.
- W2617492878 cites W2043302266 @default.
- W2617492878 cites W2045386294 @default.
- W2617492878 cites W2047406811 @default.
- W2617492878 cites W2051187290 @default.
- W2617492878 cites W2062057471 @default.
- W2617492878 cites W2062347464 @default.
- W2617492878 cites W2065309674 @default.
- W2617492878 cites W2066877229 @default.
- W2617492878 cites W2069235201 @default.
- W2617492878 cites W2069739722 @default.
- W2617492878 cites W2071827387 @default.
- W2617492878 cites W2077889102 @default.
- W2617492878 cites W2087096562 @default.
- W2617492878 cites W2095110534 @default.
- W2617492878 cites W2105249240 @default.
- W2617492878 cites W2123615285 @default.
- W2617492878 cites W2128931792 @default.
- W2617492878 cites W2131350133 @default.
- W2617492878 cites W2134155476 @default.
- W2617492878 cites W2143673345 @default.
- W2617492878 cites W2144273422 @default.
- W2617492878 cites W2157624209 @default.
- W2617492878 cites W2168708102 @default.
- W2617492878 cites W2171635616 @default.
- W2617492878 cites W2316358621 @default.
- W2617492878 cites W2322862836 @default.
- W2617492878 cites W4211171284 @default.
- W2617492878 cites W4245397386 @default.
- W2617492878 cites W79661603 @default.
- W2617492878 cites W829387965 @default.
- W2617492878 doi "https://doi.org/10.1016/j.ica.2017.05.064" @default.
- W2617492878 hasPublicationYear "2018" @default.
- W2617492878 type Work @default.
- W2617492878 sameAs 2617492878 @default.
- W2617492878 citedByCount "13" @default.
- W2617492878 countsByYear W26174928782018 @default.
- W2617492878 countsByYear W26174928782019 @default.
- W2617492878 countsByYear W26174928782020 @default.
- W2617492878 countsByYear W26174928782021 @default.
- W2617492878 countsByYear W26174928782022 @default.
- W2617492878 crossrefType "journal-article" @default.
- W2617492878 hasAuthorship W2617492878A5011020902 @default.
- W2617492878 hasAuthorship W2617492878A5023603809 @default.
- W2617492878 hasAuthorship W2617492878A5036342296 @default.
- W2617492878 hasAuthorship W2617492878A5057581236 @default.
- W2617492878 hasAuthorship W2617492878A5068080494 @default.
- W2617492878 hasAuthorship W2617492878A5070005792 @default.
- W2617492878 hasAuthorship W2617492878A5074901927 @default.
- W2617492878 hasAuthorship W2617492878A5077319795 @default.
- W2617492878 hasAuthorship W2617492878A5087638225 @default.
- W2617492878 hasConcept C145148216 @default.
- W2617492878 hasConcept C178790620 @default.
- W2617492878 hasConcept C179104552 @default.
- W2617492878 hasConcept C185592680 @default.
- W2617492878 hasConcept C2777660389 @default.
- W2617492878 hasConcept C34814092 @default.
- W2617492878 hasConcept C544778455 @default.
- W2617492878 hasConcept C8010536 @default.
- W2617492878 hasConceptScore W2617492878C145148216 @default.
- W2617492878 hasConceptScore W2617492878C178790620 @default.