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- W2617558546 endingPage "6580" @default.
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- W2617558546 abstract "Slow addition of sodium nitrite allows the in situ preparation of highly explosive diazo compounds and enables their safe and scalable application in iron catalyzed rearrangement reactions of allylic and propargylic sulfides. With catalyst loadings as low as 0.1 mol% an effective entry into α-mercapto-nitriles, α-mercapto-esters and α-trifluoromethyl-sulfides on a gram-scale is achieved." @default.
- W2617558546 created "2017-06-05" @default.
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- W2617558546 date "2017-01-01" @default.
- W2617558546 modified "2023-09-24" @default.
- W2617558546 title "Enabling iron catalyzed Doyle–Kirmse rearrangement reactions with in situ generated diazo compounds" @default.
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- W2617558546 doi "https://doi.org/10.1039/c7cc02801f" @default.
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