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- W2617659810 endingPage "2560" @default.
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- W2617659810 abstract "Post-polymerization modification is an important synthetic method to produce macromolecules with various chemical and physical properties. With this technique, functional groups of polymer molecules within the same structural scaffold can be varied, and thus, accurate research on structure-property relationships is possible. To add practicality, the direct post-polymerization of commodity polymers has been pursued, but only limited success has been realized. In this report, a study on various transesterification methods for the synthesis of functional polyacrylates beginning with a poly(methyl acrylate) (PMA), one common acrylate polymer, is presented. The Zn-based catalytic system, a combination of Zn4(OCOCF3)6O and 4-dimethylaminopyridine with instant methanol removal, exhibited the highest reactivity among many catalysts and conditions. Assorted alcohols were reacted with PMA to produce the corresponding polyacrylates. This method was successfully extended to post-polymerization modification of a PMA-containing block copolymer, PS-b-PMA and synthesis of acrylate copolymers with functional group density control. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2554–2560" @default.
- W2617659810 created "2017-06-05" @default.
- W2617659810 creator A5090197814 @default.
- W2617659810 date "2017-05-29" @default.
- W2617659810 modified "2023-09-26" @default.
- W2617659810 title "Direct transesterification of poly(methyl acrylate) for functional polyacrylate syntheses" @default.
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- W2617659810 doi "https://doi.org/10.1002/pola.28659" @default.
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