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• W2618857578 abstract "An efficient and stereocontrolled synthesis of (20S)-camptothecin and an analogue has been developed. The key feature of this synthesis is the organocatalyzed asymmetric α-hydroxylation of the lactone precursor 4 to construct its stereocenter, providing tricyclic hydroxylactone 2 in 90% yield and with 88% enantioselectivity. The precursor 4 was efficiently synthesized from the known pyridine 5 in three steps." @default.
• W2618857578 created "2017-06-05" @default.
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• W2618857578 date "2017-06-01" @default.
• W2618857578 modified "2023-09-30" @default.
• W2618857578 title "An improved synthesis of (20 S )-camptothecin and its analogue via an asymmetric α-hydroxylation with a chiral organocatalyst" @default.
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• W2618857578 doi "https://doi.org/10.1016/j.tetasy.2017.04.013" @default.
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