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- W2618860850 abstract "The formation of [{CoII(teta)2}{CoII2(tren)(teta)2}VIV15SbIII6O42(H2O)]·ca.9H2O [teta = triethylenetetraamine; tren = tris(2-aminoethyl)amine] illustrates a strategy toward reducing the molecular charge of polyoxovanadates, a key challenge in their use as components in single-molecule electronics. Here, a V–O–Co bond to a binuclear Co2+-centered complex and a Sb–N bond to the terminal N atom of a teta ligand of a mononuclear Co2+ complex allow for full charge compensation of the archetypal molecular magnet [V15Sb6O42(H2O)]6–. Density functional theory based electron localization function analysis demonstrates that the Sb–N bond has an electron density similar to that of a Sb–O bond. Magnetic exchange coupling between the VIV and CoII spin centers mediated via the Sb–N bridge is comparably weakly antiferromagnetic." @default.
- W2618860850 created "2017-06-05" @default.
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- W2618860850 date "2017-05-25" @default.
- W2618860850 modified "2023-10-12" @default.
- W2618860850 title "Covalent Co–O–V and Sb–N Bonds Enable Polyoxovanadate Charge Control" @default.
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- W2618860850 doi "https://doi.org/10.1021/acs.inorgchem.7b00724" @default.
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