FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2619016158> ?p ?o ?g. }

• W2619016158 endingPage "11569" @default.
• W2619016158 startingPage "11560" @default.
• W2619016158 abstract "A neutral N-heterocyclic phosphenium complex of manganese was synthesised by a metathesis approach and characterised by IR, NMR, and XRD studies. The short P-Mn distance suggests a substantial metal-ligand double bond character. Reaction with a hydride produced an anionic phosphine complex, which was also characterised by IR and NMR spectroscopy and, after anion exchange, a single-crystal XRD study. Protonation of the anion occurs at the metal to yield a neutral phosphine metal carbonyl hydride, which releases dihydrogen upon irradiation with UV light. These reactions confirm the electrophilic nature of the phosphenium ligand and suggest that the title complex might undergo reactions displaying metal-ligand cooperativity. Surprisingly, reaction with ammonia borane (AB) did not proceed under transfer hydrogenation of the Mn=P double bond but through the catalytic dehydrogenation of AB. The phosphenium complex behaves here as a class II catalyst, which dehydrogenates AB to NH2 BH2 that was trapped with cyclohexene. Computational model studies led to the identification of two possible catalytic cycles, which differ in the regioselectivity of the initial AB activation step. In one case, the activation proceeds as cooperative transfer hydrogenation of the Mn=P bond, whereas in the other case a H+ /H- pair is transferred to the phosphorus atom and a nitrogen atom of the phosphenium unit, resulting in a ligand-centred reaction in which the metal fragment acts merely as stabilising substituent. Unexpectedly, this pathway, which constitutes a new reaction mode for phosphenium complexes, seems to be better in accord with experimental findings on the course of the catalysis." @default.
• W2619016158 created "2017-06-05" @default.
• W2619016158 creator A5005726836 @default.
• W2619016158 creator A5043452704 @default.
• W2619016158 creator A5051029503 @default.
• W2619016158 creator A5081630396 @default.
• W2619016158 creator A5091161107 @default.
• W2619016158 creator A5091668895 @default.
• W2619016158 date "2017-07-21" @default.
• W2619016158 modified "2023-10-13" @default.
• W2619016158 title "N-Heterocyclic Phosphenium Complex of Manganese: Synthesis and Catalytic Activity in Ammonia Borane Dehydrogenation" @default.
• W2619016158 cites W1504277857 @default.
• W2619016158 cites W1897198241 @default.
• W2619016158 cites W1964280200 @default.
• W2619016158 cites W1968520751 @default.
• W2619016158 cites W1970504980 @default.
• W2619016158 cites W1972283895 @default.
• W2619016158 cites W1975693679 @default.
• W2619016158 cites W1980247048 @default.
• W2619016158 cites W1980690337 @default.
• W2619016158 cites W1988091937 @default.
• W2619016158 cites W1990108593 @default.
• W2619016158 cites W2003270732 @default.
• W2619016158 cites W2009794593 @default.
• W2619016158 cites W2013160605 @default.
• W2619016158 cites W2015517769 @default.
• W2619016158 cites W2016538866 @default.
• W2619016158 cites W2019437299 @default.
• W2619016158 cites W2022566395 @default.
• W2619016158 cites W2023174370 @default.
• W2619016158 cites W2026637040 @default.
• W2619016158 cites W2028842391 @default.
• W2619016158 cites W2030849647 @default.
• W2619016158 cites W2035862562 @default.
• W2619016158 cites W2036255768 @default.
• W2619016158 cites W2040416874 @default.
• W2619016158 cites W2044154474 @default.
• W2619016158 cites W2051789749 @default.
• W2619016158 cites W2055323558 @default.
• W2619016158 cites W2059557791 @default.
• W2619016158 cites W2061659334 @default.
• W2619016158 cites W2065215071 @default.
• W2619016158 cites W2065712148 @default.
• W2619016158 cites W2066621373 @default.
• W2619016158 cites W2070132134 @default.
• W2619016158 cites W2073931017 @default.
• W2619016158 cites W2079249553 @default.
• W2619016158 cites W2079913625 @default.
• W2619016158 cites W2082798559 @default.
• W2619016158 cites W2091554084 @default.
• W2619016158 cites W2092006330 @default.
• W2619016158 cites W2093939830 @default.
• W2619016158 cites W2097149095 @default.
• W2619016158 cites W2104832843 @default.
• W2619016158 cites W2106315920 @default.
• W2619016158 cites W2112850441 @default.
• W2619016158 cites W2127595119 @default.
• W2619016158 cites W2129152335 @default.
• W2619016158 cites W2130656773 @default.
• W2619016158 cites W2131350133 @default.
• W2619016158 cites W2131400546 @default.
• W2619016158 cites W2142839187 @default.
• W2619016158 cites W2157063862 @default.
• W2619016158 cites W2165641851 @default.
• W2619016158 cites W2207680172 @default.
• W2619016158 cites W2263985178 @default.
• W2619016158 cites W2294512153 @default.
• W2619016158 cites W2312364503 @default.
• W2619016158 cites W2315277040 @default.
• W2619016158 cites W2316125765 @default.
• W2619016158 cites W2317147387 @default.
• W2619016158 cites W2330902047 @default.
• W2619016158 cites W2331402506 @default.
• W2619016158 cites W2523290526 @default.
• W2619016158 cites W2566627581 @default.
• W2619016158 cites W2956122686 @default.
• W2619016158 doi "https://doi.org/10.1002/chem.201701442" @default.
• W2619016158 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28560855" @default.
• W2619016158 hasPublicationYear "2017" @default.
• W2619016158 type Work @default.
• W2619016158 sameAs 2619016158 @default.
• W2619016158 citedByCount "38" @default.
• W2619016158 countsByYear W26190161582017 @default.
• W2619016158 countsByYear W26190161582018 @default.
• W2619016158 countsByYear W26190161582019 @default.
• W2619016158 countsByYear W26190161582020 @default.
• W2619016158 countsByYear W26190161582021 @default.
• W2619016158 countsByYear W26190161582022 @default.
• W2619016158 countsByYear W26190161582023 @default.
• W2619016158 crossrefType "journal-article" @default.
• W2619016158 hasAuthorship W2619016158A5005726836 @default.
• W2619016158 hasAuthorship W2619016158A5043452704 @default.
• W2619016158 hasAuthorship W2619016158A5051029503 @default.
• W2619016158 hasAuthorship W2619016158A5081630396 @default.
• W2619016158 hasAuthorship W2619016158A5091161107 @default.
• W2619016158 hasAuthorship W2619016158A5091668895 @default.
• W2619016158 hasConcept C116569031 @default.
• W2619016158 hasConcept C145148216 @default.

• next