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- W2619030581 abstract "A regiospecific access to 3-haloquinolines has been developed via a three-component annulation of aryldiazonium salts, nitriles and haloalkynes. This reaction proceeds through an initial formation of reactive nitrilium ion and further cascade annulation with haloalkynes. This method provides a straightforward access to a diverse array of functionalized quinolones (28 examples) under mild conditions and exhibits broad functional group tolerance. Applications of this method in a gram scale reaction and a formal synthesis of Pitavastatin are illustrated." @default.
- W2619030581 created "2017-06-05" @default.
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- W2619030581 creator A5077249409 @default.
- W2619030581 date "2017-07-01" @default.
- W2619030581 modified "2023-09-26" @default.
- W2619030581 title "Cascade annulations of aryldiazonium salts, nitriles and halo-alkynes leading to 3-haloquinolines" @default.
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- W2619030581 doi "https://doi.org/10.1016/j.tet.2017.05.085" @default.
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