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• W2619191718 endingPage "2936" @default.
• W2619191718 startingPage "2933" @default.
• W2619191718 abstract "The mercuration of calix[4]arene immobilized in the cone conformation allowed the introduction of an amino group at the meta position of the basic skeleton. Acylation and subsequent intramolecular Bischler–Napieralski-type cyclization led to a novel type of bridged calixarene containing a seven-membered ring. These compounds with an enlarged and rigidified cavity represent a unique and inherently chiral system that may potentially be applicable for the design of chiral receptors. The absolute configuration of one enantiomer, obtained by resolution of the racemate using chiral HPLC, was assigned by single-crystal structure determination." @default.
• W2619191718 created "2017-06-05" @default.
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• W2619191718 date "2017-05-22" @default.
• W2619191718 modified "2023-10-16" @default.
• W2619191718 title "Inherently Chiral Upper-Rim-Bridged Calix[4]arenes Possessing a Seven Membered Ring" @default.
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• W2619191718 doi "https://doi.org/10.1021/acs.orglett.7b01170" @default.
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