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- W2619271393 abstract "The synthesis and structural characterization of the new olefinic complex [Rh(η 5 ‐C 5 H 5 )(coe) 2 ] ( 2 ) (coe = cis ‐cyclooctene) is reported. The title compound could easily be prepared in good yield by reaction of [{Rh(μ‐Cl)(coe) 2 } 2 ] ( 1 ) with an appropriate amount of thallium cyclopentadienide in THF at room temperature. Single crystals of 2 were grown from n ‐hexane and were analyzed by X‐ray crystallography. In a similar manner the compound [Rh(η 5 ‐C 5 H 5 )(cod)] ( 4 ) (cod = cis , cis ‐1.5‐cyclooctadiene) was obtained from [{Rh(μ‐Cl)(cod)} 2 ] and thallium cyclopentadienide in THF at room temperature and was characterized by spectroscopic means as well as by X‐ray diffraction." @default.
- W2619271393 created "2017-06-05" @default.
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- W2619271393 date "2017-05-30" @default.
- W2619271393 modified "2023-09-27" @default.
- W2619271393 title "Synthesis and Molecular Structures of [Rh(η <sup>5</sup> ‐C <sub>5</sub> H <sub>5</sub> )(coe) <sub>2</sub> ] (coe = <i>cis</i> ‐cyclooctene) and [Rh(η <sup>5</sup> ‐C <sub>5</sub> H <sub>5</sub> )(cod)] (cod = <i>cis</i> , <i>cis</i> ‐η <sup>4</sup> ‐1,5‐cyclooctadiene)" @default.
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- W2619271393 doi "https://doi.org/10.1002/zaac.201700150" @default.
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