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- W2619479580 abstract "Abstract We report an efficient energy storage electrode based on well-defined, interconnected NiO nanosheets (NiO-NS) grown directly on a mesoporous TiN ( meso -TiN) film via a solvothermal method. A mesoporous TiO 2 ( meso -TiO 2 ) film is prepared using a graft copolymer template and then thermally annealed in ammonia at 800 °C to convert meso -TiO 2 into meso -TiN. The ultrathin interconnected NiO-NS provide a large surface area and effective electron pathway, which enhance their specific capacitance and electrochemical properties. In contrast, a less-organized structure with poor homogeneity, low porosity and some cracks is formed for dense-TiN film prepared without the PVC-g-POEM. The meso -TiN film acts as an efficient conductive support to grow the NiO-NS and enhances the diffusion of electron/electrolyte ions. Despite its low thickness ( meso -TiN supercapacitor exhibits a high capacitance of 104 mF cm −2 and good cycle stability (86% capacitance retention) owing to the synergetic effects of the NiO-NS and meso -TiN heteronanostructure. The NiO-NS/ meso -TiN film is also applied to a flexible substrate and exhibits no cracks after bending; thus, our work provides an efficient way to design flexible energy storage devices using graft-copolymer-directed heteronanostructures." @default.
- W2619479580 created "2017-06-05" @default.
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- W2619479580 date "2017-10-01" @default.
- W2619479580 modified "2023-09-24" @default.
- W2619479580 title "Direct growth of NiO nanosheets on mesoporous TiN film for energy storage devices" @default.
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- W2619479580 doi "https://doi.org/10.1016/j.apsusc.2017.05.216" @default.
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