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• W2619510290 abstract "The [1,3]-alkoxy rearrangement reactions of N-alkoxyanilines were efficiently catalyzed by cationic N-heterocyclic carbene (NHC)-Cu catalysts in affording 2-alkoxyaniline derivatives in good to excellent yields with high functional group compatibility. For N-alkoxyanilines having an electron-withdrawing substituent at the meta-position, the alkoxy group selectively migrated to the more hindered ortho-position. In contrast, the alkoxy group migrated to the less hindered ortho-position for N-alkoxyanilines having an electron-donating substituent. Mechanistic studies suggest that the rearrangement reactions proceed via an intramolecular route." @default.
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• W2619510290 date "2017-05-24" @default.
• W2619510290 modified "2023-10-03" @default.
• W2619510290 title "Cationic <i>N</i>-Heterocyclic Carbene Copper-Catalyzed [1,3]-Alkoxy Rearrangement of <i>N-</i>Alkoxyanilines" @default.
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• W2619510290 doi "https://doi.org/10.1021/acs.orglett.7b01110" @default.
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