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- W2620003209 abstract "The reaction between (NH4)2TiF6 and H3BO3 in the presence of varying quantities of PEG-6000 was used to form NH4TiOF3 mesocrystals (MCs). The amount of PEG-6000, employed as a template, is crucial to the formation of defect free, non-agglomerated NH4TiOF3 MCs; high concentrations lead to MC agglomeration, lower ones result in centralized defects. This polymer-mediated formation process may be understood using an analogy with known polymerization reactions. The oxofluorotitanate MCs readily undergo a thermal topotactic transformation to give anatase MCs with photocatalytic activity. The TiO2 MCs are porous, with highly orientated lamellar crystallites that form part of the larger mesocrystal structure." @default.
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- W2620003209 date "2017-01-01" @default.
- W2620003209 modified "2023-10-18" @default.
- W2620003209 title "New insights into polymer mediated formation of anatase mesocrystals" @default.
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- W2620003209 doi "https://doi.org/10.1039/c6ce01985d" @default.
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