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- W2620007951 abstract "A new and efficient method for the synthesis of unsymmetrical 1,3-butadiynes by gold-catalyzed C(sp)-C(sp) cross-coupling of terminal alkynes with alkynyl hypervalent iodine(III) reagents has been developed. The reaction features high selectivity and efficiency, mild reaction conditions, wide substrate scope, and functional-group compatibility, and is a highly attractive complement to existing methods. Mechanistic studies reveal that formation of a phenanthrolinyl-ligated gold(I) complex is crucial for the efficiency and selectivity of the target transformation." @default.
- W2620007951 created "2017-06-05" @default.
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- W2620007951 date "2017-05-22" @default.
- W2620007951 modified "2023-10-12" @default.
- W2620007951 title "Gold-Catalyzed Cadiot-Chodkiewicz-type Cross-Coupling of Terminal Alkynes with Alkynyl Hypervalent Iodine Reagents: Highly Selective Synthesis of Unsymmetrical 1,3-Diynes" @default.
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- W2620007951 doi "https://doi.org/10.1002/anie.201702833" @default.
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