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• W2620076474 abstract "A series of novel oxazoline-substituted imidazolium salts with planar and central chirality has been successfully synthesized and applied to copper-catalyzed enantioselective 1,2-silylation of N-tosylaldimines. The oxazoline–carbene copper complex generated in situ by the reaction of the oxazoline-substituted imidazolium and Cu2O demonstrated an exceptionally high catalytic activity in the asymmetric 1,2-silylation of N-tosylaldimines, affording chiral α-amino silanes with excellent yields and enantioselectivities." @default.
• W2620076474 created "2017-06-05" @default.
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• W2620076474 date "2017-06-01" @default.
• W2620076474 modified "2023-10-17" @default.
• W2620076474 title "Synthesis of [2.2]paracyclophane-based bidentate oxazoline–carbene ligands for the asymmetric 1,2-silylation of N -tosylaldimines" @default.
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• W2620076474 doi "https://doi.org/10.1016/j.tetasy.2017.05.001" @default.
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