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• W2620228885 startingPage "8746" @default.
• W2620228885 abstract "Doping in perovskite nanocrystals adopts different mechanistic approach in comparison to widely established doping in chalcogenide quantum dots. The fast formation of perovskites makes the dopant insertions more competitive and challenging. Introducing alkylamine hydrochloride (RNH3 Cl) as a promoting reagent, precise controlled doping of MnII in CsPbCl3 perovskite nanocrystals is reported. Simply, by changing the amount of RNH3 Cl, the Mn incorporation and subsequent tuning in the excitonic as well as Mn d-d emission intensities are tailored. Investigations suggested that RNH3 Cl acted as the chlorinating source, controlled the size, and also helps in increasing the number of particles. This provided more opportunity for Mn ions to take part in reaction and occupied the appropriate lattice positions. Carrying out several reactions with varying reaction parameters, the doping conditions are optimized and the role of the promoting reagent for both doped and undoped systems are compared." @default.
• W2620228885 created "2017-06-05" @default.
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• W2620228885 date "2017-06-22" @default.
• W2620228885 modified "2023-09-27" @default.
• W2620228885 title "Chemically Tailoring the Dopant Emission in Manganese-Doped CsPbCl₃ Perovskite Nanocrystals" @default.
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• W2620228885 doi "https://doi.org/10.1002/anie.201703863" @default.
• W2620228885 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28557185" @default.
• W2620228885 hasPublicationYear "2017" @default.
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