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• W2620259583 endingPage "1190" @default.
• W2620259583 startingPage "1183" @default.
• W2620259583 abstract "Reaction between EuCl 3 and the ligand 1,3-di(thien-2-yl)propane-1,3-dione (L) leads to luminescent coordination compounds [EuL 3 (EtOH) 2 ] (1), [EuL 2 (i-PrOH) 4 ]Cl (2) and [EuL 3 (i-PrOH) 2 ] (3), isolated as single crystals in high yield (70%–95%). The Eu/β-diketonate ratio is tuned from 1:2 to 1:3 through the variation of the alcoholic solvent (ethanol and isopropanol) or the base (pyridine and NaOH). In all compounds, Eu 3+ ions are eight-coordinated, and in 2, the molecules are arranged in an H-bond supported supramolecular 1D chain. These compositional and structural differences are reflected also on the absorption and emission properties." @default.
• W2620259583 created "2017-06-05" @default.
• W2620259583 creator A5010513254 @default.
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• W2620259583 date "2017-11-01" @default.
• W2620259583 modified "2023-09-27" @default.
• W2620259583 title "Easy but not straightforward: base and solvent effect on the synthesis of luminescent europium 1,3-di(thien-2-yl)propane-1,3-dionate coordination complexes" @default.
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• W2620259583 doi "https://doi.org/10.1139/cjc-2017-0200" @default.
• W2620259583 hasPublicationYear "2017" @default.
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