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• W2620342026 startingPage "9039" @default.
• W2620342026 abstract "Abstract The ability to tune between different regioselectivities using a common pre‐catalyst is an unusual yet highly desirable process. Here, we report the use of an iron(II) pre‐catalyst that can be used to synthesize vinyl phosphines in a Markovnikov‐selective manner in benzene, whereas a simple change to dichloromethane as the reaction solvent leads to the Z ‐selective anti ‐Markovnikov product. Preliminary mechanistic studies are reported that suggest Markovnikov selectivity is a radical‐mediated process, whereas the anti ‐Markovnikov selectivity is not radical in nature but is due to a change in oxidation state." @default.
• W2620342026 created "2017-06-05" @default.
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• W2620342026 date "2017-06-19" @default.
• W2620342026 modified "2023-10-12" @default.
• W2620342026 title "Markovnikov versus<i>anti</i>-Markovnikov Hydrophosphination: Divergent Reactivity Using an Iron(II) β-Diketiminate Pre-Catalyst" @default.
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• W2620342026 doi "https://doi.org/10.1002/chem.201702374" @default.
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