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- W2620625391 abstract "Abstract The first catalytic oxygenative allylic transposition of unactivated alkenes into enones has been developed using an oxoammonium salt as the catalyst. This reaction converts various tri‐ and trans ‐disubstituted alkenes into their corresponding enones with transposition of their double bonds at ambient temperature in good yields. The use of a less‐hindered azaadamantane‐type oxoammonium salt as the catalyst and a combination of two distinct stoichiometric oxidants, namely, iodobenzene diacetate and magnesium monoperoxyphthalate hexahydrate (MMPP⋅6 H 2 O) are essential to facilitate the enone formation efficiently." @default.
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- W2620625391 date "2017-07-12" @default.
- W2620625391 modified "2023-10-06" @default.
- W2620625391 title "Catalytic Oxygenative Allylic Transposition of Alkenes into Enones with an Azaadamantane‐Type Oxoammonium Salt Catalyst" @default.
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- W2620625391 doi "https://doi.org/10.1002/chem.201702512" @default.
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