Matches in SemOpenAlex for { <https://semopenalex.org/work/W2621032912> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2621032912 endingPage "32" @default.
- W2621032912 startingPage "24" @default.
- W2621032912 abstract "Two neutral polyhydroxylated silica bonded stationary phases, namely maltose-silica (MALT-silica) and sorbitol-silica (SOR-silica), have been introduced and chromatographically characterized in hydrophilic interaction liquid chromatography (HILIC) for a wide range of polar compounds. The bonding of the maltose and sorbitol to the silica surface was brought about by first converting bare silica to an epoxy-activated silica surface via reaction with γ-glycidoxypropyltrimethoxysilane (GPTMS) followed by attaching maltose and sorbitol to the epoxy surface in the presence of the Lewis acid catalyst BF3.ethereate. Both silica based columns offered the expected retention characteristics usually encountered for neutral polar surface. The retention mechanism is majorly based on solute’ differential partitioning between an organic rich hydro-organic mobile phase (e.g., ACN rich mobile phase) and an adsorbed water layer on the surface of the stationary phase although additional hydrogen bonding was also responsible in some cases for solute retention. The MALT-silica column proved to be more hydrophilic and offered higher retention, separation efficiency and resolution than the SOR-silica column among the tested polar solutes such as derivatized mono- and oligosaccharides, weak phenolic acids, cyclic nucleotide monophosphate and nucleotide-5′-monophosphates, and weak bases, e.g., nucleobases and nucleosides." @default.
- W2621032912 created "2017-06-09" @default.
- W2621032912 creator A5036104491 @default.
- W2621032912 creator A5089753271 @default.
- W2621032912 date "2017-07-01" @default.
- W2621032912 modified "2023-10-16" @default.
- W2621032912 title "Polar silica-based stationary phases. Part II- Neutral silica stationary phases with surface bound maltose and sorbitol for hydrophilic interaction liquid chromatography" @default.
- W2621032912 cites W1869061692 @default.
- W2621032912 cites W1915945775 @default.
- W2621032912 cites W1986750273 @default.
- W2621032912 cites W1987434999 @default.
- W2621032912 cites W1988767607 @default.
- W2621032912 cites W2003826181 @default.
- W2621032912 cites W2004440057 @default.
- W2621032912 cites W2010927362 @default.
- W2621032912 cites W2012194551 @default.
- W2621032912 cites W2015466408 @default.
- W2621032912 cites W2021142047 @default.
- W2621032912 cites W2048549145 @default.
- W2621032912 cites W2050767161 @default.
- W2621032912 cites W2064109088 @default.
- W2621032912 cites W2065782393 @default.
- W2621032912 cites W2068922516 @default.
- W2621032912 cites W2085904163 @default.
- W2621032912 cites W2089844732 @default.
- W2621032912 cites W2100153288 @default.
- W2621032912 cites W2106333441 @default.
- W2621032912 cites W2133099033 @default.
- W2621032912 cites W2168778562 @default.
- W2621032912 cites W2468603960 @default.
- W2621032912 cites W2514450697 @default.
- W2621032912 cites W2520037224 @default.
- W2621032912 cites W2520104296 @default.
- W2621032912 cites W2592679136 @default.
- W2621032912 doi "https://doi.org/10.1016/j.chroma.2017.05.059" @default.
- W2621032912 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28599861" @default.
- W2621032912 hasPublicationYear "2017" @default.
- W2621032912 type Work @default.
- W2621032912 sameAs 2621032912 @default.
- W2621032912 citedByCount "10" @default.
- W2621032912 countsByYear W26210329122017 @default.
- W2621032912 countsByYear W26210329122018 @default.
- W2621032912 countsByYear W26210329122020 @default.
- W2621032912 countsByYear W26210329122021 @default.
- W2621032912 countsByYear W26210329122022 @default.
- W2621032912 countsByYear W26210329122023 @default.
- W2621032912 crossrefType "journal-article" @default.
- W2621032912 hasAuthorship W2621032912A5036104491 @default.
- W2621032912 hasAuthorship W2621032912A5089753271 @default.
- W2621032912 hasConcept C116817701 @default.
- W2621032912 hasConcept C121332964 @default.
- W2621032912 hasConcept C1276947 @default.
- W2621032912 hasConcept C150394285 @default.
- W2621032912 hasConcept C178790620 @default.
- W2621032912 hasConcept C179998833 @default.
- W2621032912 hasConcept C185592680 @default.
- W2621032912 hasConcept C2776779347 @default.
- W2621032912 hasConcept C2778197599 @default.
- W2621032912 hasConcept C2778597767 @default.
- W2621032912 hasConcept C2779532046 @default.
- W2621032912 hasConcept C29705727 @default.
- W2621032912 hasConcept C43617362 @default.
- W2621032912 hasConceptScore W2621032912C116817701 @default.
- W2621032912 hasConceptScore W2621032912C121332964 @default.
- W2621032912 hasConceptScore W2621032912C1276947 @default.
- W2621032912 hasConceptScore W2621032912C150394285 @default.
- W2621032912 hasConceptScore W2621032912C178790620 @default.
- W2621032912 hasConceptScore W2621032912C179998833 @default.
- W2621032912 hasConceptScore W2621032912C185592680 @default.
- W2621032912 hasConceptScore W2621032912C2776779347 @default.
- W2621032912 hasConceptScore W2621032912C2778197599 @default.
- W2621032912 hasConceptScore W2621032912C2778597767 @default.
- W2621032912 hasConceptScore W2621032912C2779532046 @default.
- W2621032912 hasConceptScore W2621032912C29705727 @default.
- W2621032912 hasConceptScore W2621032912C43617362 @default.
- W2621032912 hasLocation W26210329121 @default.
- W2621032912 hasLocation W26210329122 @default.
- W2621032912 hasOpenAccess W2621032912 @default.
- W2621032912 hasPrimaryLocation W26210329121 @default.
- W2621032912 hasRelatedWork W1975954650 @default.
- W2621032912 hasRelatedWork W1986422890 @default.
- W2621032912 hasRelatedWork W2009234699 @default.
- W2621032912 hasRelatedWork W2015466408 @default.
- W2621032912 hasRelatedWork W2040905622 @default.
- W2621032912 hasRelatedWork W2070636802 @default.
- W2621032912 hasRelatedWork W2159072602 @default.
- W2621032912 hasRelatedWork W2571272986 @default.
- W2621032912 hasRelatedWork W2785946134 @default.
- W2621032912 hasRelatedWork W4366599269 @default.
- W2621032912 hasVolume "1508" @default.
- W2621032912 isParatext "false" @default.
- W2621032912 isRetracted "false" @default.
- W2621032912 magId "2621032912" @default.
- W2621032912 workType "article" @default.