Matches in SemOpenAlex for { <https://semopenalex.org/work/W2621262021> ?p ?o ?g. }
- W2621262021 endingPage "7740" @default.
- W2621262021 startingPage "7737" @default.
- W2621262021 abstract "The catalytic enantioselective preparation of densely functionalized amines is a fundamental synthetic challenge. To address this challenge, we report for the first time that the Winstein rearrangement can be enlisted as the racemization pathway in a dynamic kinetic resolution of allylic azides. Alkene functionalization by Sharpless dihydroxylation affords tertiary azides in excellent enantioselectivity (up to 99:1 er). This approach establishes the chirality of the tertiary azide, obviates the need to directly forge either a congested C–N or C–C bond at the new nitrogenous stereocenter, and establishes additional functionality. Several examples demonstrate further elaboration of this functionality." @default.
- W2621262021 created "2017-06-09" @default.
- W2621262021 creator A5017740601 @default.
- W2621262021 creator A5021998784 @default.
- W2621262021 creator A5070974899 @default.
- W2621262021 date "2017-06-05" @default.
- W2621262021 modified "2023-10-07" @default.
- W2621262021 title "Dynamic Kinetic Resolution of Allylic Azides via Asymmetric Dihydroxylation" @default.
- W2621262021 cites W1408999646 @default.
- W2621262021 cites W1910075499 @default.
- W2621262021 cites W1969431500 @default.
- W2621262021 cites W1983586859 @default.
- W2621262021 cites W1988614723 @default.
- W2621262021 cites W1992756987 @default.
- W2621262021 cites W2011040374 @default.
- W2621262021 cites W2016741858 @default.
- W2621262021 cites W2021336304 @default.
- W2621262021 cites W2024444656 @default.
- W2621262021 cites W2027189159 @default.
- W2621262021 cites W2027276718 @default.
- W2621262021 cites W2044510640 @default.
- W2621262021 cites W2052928794 @default.
- W2621262021 cites W2065968122 @default.
- W2621262021 cites W2075813623 @default.
- W2621262021 cites W2076658253 @default.
- W2621262021 cites W2081007614 @default.
- W2621262021 cites W2082427343 @default.
- W2621262021 cites W2086765155 @default.
- W2621262021 cites W2090616267 @default.
- W2621262021 cites W2094839826 @default.
- W2621262021 cites W2119122362 @default.
- W2621262021 cites W2146318727 @default.
- W2621262021 cites W2158088781 @default.
- W2621262021 cites W2278002274 @default.
- W2621262021 cites W2282794059 @default.
- W2621262021 cites W2309928293 @default.
- W2621262021 cites W2323310309 @default.
- W2621262021 cites W2337203343 @default.
- W2621262021 cites W2337760095 @default.
- W2621262021 cites W2398961479 @default.
- W2621262021 cites W2402091274 @default.
- W2621262021 cites W2409675315 @default.
- W2621262021 cites W2512424814 @default.
- W2621262021 cites W2522757959 @default.
- W2621262021 cites W2580181279 @default.
- W2621262021 cites W2587433337 @default.
- W2621262021 cites W2593898431 @default.
- W2621262021 cites W2606353208 @default.
- W2621262021 cites W2949687468 @default.
- W2621262021 cites W2949995997 @default.
- W2621262021 cites W2950749569 @default.
- W2621262021 cites W2950801698 @default.
- W2621262021 cites W2952717383 @default.
- W2621262021 cites W2953011238 @default.
- W2621262021 cites W4210988199 @default.
- W2621262021 cites W4235471853 @default.
- W2621262021 doi "https://doi.org/10.1021/jacs.7b04203" @default.
- W2621262021 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28574252" @default.
- W2621262021 hasPublicationYear "2017" @default.
- W2621262021 type Work @default.
- W2621262021 sameAs 2621262021 @default.
- W2621262021 citedByCount "33" @default.
- W2621262021 countsByYear W26212620212017 @default.
- W2621262021 countsByYear W26212620212018 @default.
- W2621262021 countsByYear W26212620212019 @default.
- W2621262021 countsByYear W26212620212020 @default.
- W2621262021 countsByYear W26212620212021 @default.
- W2621262021 countsByYear W26212620212022 @default.
- W2621262021 countsByYear W26212620212023 @default.
- W2621262021 crossrefType "journal-article" @default.
- W2621262021 hasAuthorship W2621262021A5017740601 @default.
- W2621262021 hasAuthorship W2621262021A5021998784 @default.
- W2621262021 hasAuthorship W2621262021A5070974899 @default.
- W2621262021 hasConcept C120095180 @default.
- W2621262021 hasConcept C121332964 @default.
- W2621262021 hasConcept C124668440 @default.
- W2621262021 hasConcept C134195300 @default.
- W2621262021 hasConcept C146686406 @default.
- W2621262021 hasConcept C161790260 @default.
- W2621262021 hasConcept C178790620 @default.
- W2621262021 hasConcept C185592680 @default.
- W2621262021 hasConcept C20621625 @default.
- W2621262021 hasConcept C21951064 @default.
- W2621262021 hasConcept C2776254738 @default.
- W2621262021 hasConcept C2777672777 @default.
- W2621262021 hasConcept C2780997848 @default.
- W2621262021 hasConcept C28173026 @default.
- W2621262021 hasConcept C52703039 @default.
- W2621262021 hasConcept C60002323 @default.
- W2621262021 hasConcept C62520636 @default.
- W2621262021 hasConcept C71240020 @default.
- W2621262021 hasConcept C7602139 @default.
- W2621262021 hasConceptScore W2621262021C120095180 @default.
- W2621262021 hasConceptScore W2621262021C121332964 @default.
- W2621262021 hasConceptScore W2621262021C124668440 @default.
- W2621262021 hasConceptScore W2621262021C134195300 @default.
- W2621262021 hasConceptScore W2621262021C146686406 @default.
- W2621262021 hasConceptScore W2621262021C161790260 @default.