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- W2621383278 abstract "The adsorption of CO 2 on supported Re catalysts have been investigated by FTIR spectroscopy. Addition of H 2 to CO 2 , initiated the dissociation on all catalysts as indicated by CO bands. Besides, new spectral features were developed, attributed to formate species. This assumption was confirmed by the adsorption of HCOOH vapor on these solids. No bands due to formate were detected on Re/SiO 2 . Adding methane and ethane to CO 2 also led to the appearance of CO bands, the intensities of which were much less compared to the H 2 + CO 2 co-adsorption. The formation of formate also occurred to a small extent. It was assumed that the formate species identified in the surface interactions is located on the support, where it is stabilized. The possible pathways of the occurrence of formate complex on the oxides are described." @default.
- W2621383278 created "2017-06-09" @default.
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- W2621383278 date "2016-05-26" @default.
- W2621383278 modified "2023-09-23" @default.
- W2621383278 title "ADSORPTION AND SURFACE REACTION OF H2 AND CO2 ON SUPPORTED CATALYSTS" @default.
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