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• W2622463764 abstract "The tortuosity–porosity relation and internal structure diameters in a selected organogel are studied. The diffusion coefficient measured by pulsed field gradient NMR at short and long observation times can be used to estimate the tortuosity and the pore surface-to-volume (S/V pore) ratio of a porous material (Latour et al. in J Magn Res A 112:83–91, 1995; Mair et al. in Magn Res Imaging 19:345–351, 2001; Mitra et al. in Phys Rev B 47(14):8565–8574, 1993; Valiullin and Skirda in J Chem Phys 114:452–458, 2001). The value of S/V pore allows to calculate the average pore and barrier diameters. In the experiment, the time-dependent diffusion coefficient of toluene in a low molecular weight gelator methyl-4,6-O-(p-nitrobenzylidene)-α-d-glucopyranoside (Gluco-NO2) matrix was measured. The results revealed the relation between the diffusion coefficient of toluene and the concentration of gelator Gluco-NO2 in the system. With increasing Gluco-NO2 compound in the sample, the diffusion coefficient of toluene decreases. On the basis of the diffusion coefficient behaviour as a function of time and gelator concentration, the fibrous structure of the gel matrix was identified and the structural parameters of the system were investigated." @default.
• W2622463764 created "2017-06-15" @default.
• W2622463764 creator A5002442276 @default.
• W2622463764 date "2017-06-09" @default.
• W2622463764 modified "2023-09-28" @default.
• W2622463764 title "The structural parameters of rigid matrix of saccharide-based gel described by short and long diffusion regime analysis" @default.
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• W2622463764 doi "https://doi.org/10.1007/s10853-017-1261-9" @default.
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