FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2623689647> ?p ?o ?g. }

• W2623689647 endingPage "307" @default.
• W2623689647 startingPage "299" @default.
• W2623689647 abstract "The transformation and detoxification of halobenzoquinones (HBQs), a class of emerging disinfection byproducts (DBPs), was studied in the presence of amino acids (AAs). The reaction activity of three HBQs with AAs generally ranked as 2-chlorobenzoquinone (CBQ) < 2,6-dichlorobezoquinone (DCBQ) < tetrachloroquinone (TCBQ), consistent with their halogenation degree and the calculated electron affinity (EA) results. According to mass spectrometry and density functional theory (DFT) calculations, AAs can easily covalently incorporate into HBQs via nucleophilic addition (CBQ and DCBQ) or substitution (TCBQ) through CNC or CSC linkages. Hydroxylation, nucleophilic reaction and decarboxylation were proposed to be the three major reaction pathways for HBQs transformation with AAs. HBQs firstly underwent the spontaneous hydrolysis, resulting in OH-HBQs formation. Then, nucleophilic addition/substitution of AAs occurred on HBQs and OH-HBQs to produce AA-HBQs/AA-HBQs-OH adducts. These adducts were subsequently oxidized into their corresponding decarboxylated forms. Based on the results of Luminous bacterium Q67 acute toxicity test, the toxicity of HBQs solution greatly decreased with AAs presented. The toxicity change was well explained by the lowest unoccupied molecular orbital energy (ELUMO) of formed products. Notably, the step that AAs nucleophilic bonded with HBQs led to the highest rise of ELUMO, which should be the most effective pathway for HBQs detoxification. This study shows that binding with amino nitrogen compounds should be an important process for HBQs transformation and detoxification, which helps to better understand the fate of this typical DBP in surface water." @default.
• W2623689647 created "2017-06-15" @default.
• W2623689647 creator A5004926020 @default.
• W2623689647 creator A5012044374 @default.
• W2623689647 creator A5027454015 @default.
• W2623689647 creator A5052722036 @default.
• W2623689647 creator A5077558661 @default.
• W2623689647 creator A5083687470 @default.
• W2623689647 date "2017-10-01" @default.
• W2623689647 modified "2023-10-09" @default.
• W2623689647 title "Transformation of halobenzoquinones with the presence of amino acids in water: Products, pathways and toxicity" @default.
• W2623689647 cites W1527076520 @default.
• W2623689647 cites W1965431138 @default.
• W2623689647 cites W1972756092 @default.
• W2623689647 cites W1981206423 @default.
• W2623689647 cites W1982258330 @default.
• W2623689647 cites W1987633665 @default.
• W2623689647 cites W1996310769 @default.
• W2623689647 cites W2001341425 @default.
• W2623689647 cites W2005120335 @default.
• W2623689647 cites W2014596830 @default.
• W2623689647 cites W2015608984 @default.
• W2623689647 cites W2024731313 @default.
• W2623689647 cites W2029084438 @default.
• W2623689647 cites W2040391336 @default.
• W2623689647 cites W2046144711 @default.
• W2623689647 cites W2054370280 @default.
• W2623689647 cites W2063673863 @default.
• W2623689647 cites W2069040311 @default.
• W2623689647 cites W2071879037 @default.
• W2623689647 cites W2081444345 @default.
• W2623689647 cites W2081767706 @default.
• W2623689647 cites W2083213659 @default.
• W2623689647 cites W2086107685 @default.
• W2623689647 cites W2090990681 @default.
• W2623689647 cites W2095358649 @default.
• W2623689647 cites W2115119143 @default.
• W2623689647 cites W2116562890 @default.
• W2623689647 cites W2146628692 @default.
• W2623689647 cites W2147742582 @default.
• W2623689647 cites W2170835997 @default.
• W2623689647 cites W2180537095 @default.
• W2623689647 cites W2252583923 @default.
• W2623689647 cites W2313054799 @default.
• W2623689647 cites W2313083755 @default.
• W2623689647 cites W2313522352 @default.
• W2623689647 cites W2314714056 @default.
• W2623689647 cites W2316540905 @default.
• W2623689647 cites W2318122998 @default.
• W2623689647 cites W2318305681 @default.
• W2623689647 cites W2324024390 @default.
• W2623689647 cites W2329480572 @default.
• W2623689647 cites W2334195826 @default.
• W2623689647 cites W2534632194 @default.
• W2623689647 doi "https://doi.org/10.1016/j.watres.2017.06.007" @default.
• W2623689647 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28614742" @default.
• W2623689647 hasPublicationYear "2017" @default.
• W2623689647 type Work @default.
• W2623689647 sameAs 2623689647 @default.
• W2623689647 citedByCount "36" @default.
• W2623689647 countsByYear W26236896472018 @default.
• W2623689647 countsByYear W26236896472019 @default.
• W2623689647 countsByYear W26236896472020 @default.
• W2623689647 countsByYear W26236896472021 @default.
• W2623689647 countsByYear W26236896472022 @default.
• W2623689647 countsByYear W26236896472023 @default.
• W2623689647 crossrefType "journal-article" @default.
• W2623689647 hasAuthorship W2623689647A5004926020 @default.
• W2623689647 hasAuthorship W2623689647A5012044374 @default.
• W2623689647 hasAuthorship W2623689647A5027454015 @default.
• W2623689647 hasAuthorship W2623689647A5052722036 @default.
• W2623689647 hasAuthorship W2623689647A5077558661 @default.
• W2623689647 hasAuthorship W2623689647A5083687470 @default.
• W2623689647 hasConcept C108204754 @default.
• W2623689647 hasConcept C116263406 @default.
• W2623689647 hasConcept C135731615 @default.
• W2623689647 hasConcept C14158195 @default.
• W2623689647 hasConcept C155647269 @default.
• W2623689647 hasConcept C161790260 @default.
• W2623689647 hasConcept C178790620 @default.
• W2623689647 hasConcept C178907741 @default.
• W2623689647 hasConcept C181199279 @default.
• W2623689647 hasConcept C185592680 @default.
• W2623689647 hasConcept C2780595602 @default.
• W2623689647 hasConcept C2781109383 @default.
• W2623689647 hasConcept C29730261 @default.
• W2623689647 hasConcept C32909587 @default.
• W2623689647 hasConcept C65973085 @default.
• W2623689647 hasConcept C71240020 @default.
• W2623689647 hasConcept C94412978 @default.
• W2623689647 hasConceptScore W2623689647C108204754 @default.
• W2623689647 hasConceptScore W2623689647C116263406 @default.
• W2623689647 hasConceptScore W2623689647C135731615 @default.
• W2623689647 hasConceptScore W2623689647C14158195 @default.
• W2623689647 hasConceptScore W2623689647C155647269 @default.
• W2623689647 hasConceptScore W2623689647C161790260 @default.
• W2623689647 hasConceptScore W2623689647C178790620 @default.
• W2623689647 hasConceptScore W2623689647C178907741 @default.

• next