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- W2623846053 abstract "Adsorption of NO and the reaction between NO and H2 were investigated on the Ru(0001) surface by X-ray photoelectron spectroscopy (XPS). Surface composition was measured after NO adsorption and after the selective catalytic reduction of nitric oxide with hydrogen in steady-state conditions at 320 K and 390 K in a 30:1 mixture of H2 and NO (total pressure = 10 4 mbar). After steady-state NO reduction, molecularly adsorbed NO in both the linear on-top and threefold coordinations, NHads and Nads species were identified by XPS. The coverage of the NHads and Nads species was higher after the reaction at 390 K than the corresponding values at 320 K. Strong destabilisation of Nads by Oads was detected. A possible reaction mechanism is discussed. 2005 Elsevier B.V. All rights reserved." @default.
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- W2623846053 date "2005-01-01" @default.
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- W2623846053 title "The catalytic reduction of NO by H-2 on Ru(0001): Observation of NHads species" @default.
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